Irreversible processes

 

Entropy production

 

The change of entropy density is given by

as it is

where we have a convective term of the entropy flow.

According to Gibbs' relation follows for the movement of the mass center

 

and with somewhere else derived terms the entropy balance equation

 

we get for the entropy flow

the entropy production

The first term in the entropy production is due to the heat conduction, the second due to the diffusion, the third due to the field velocity gradient with viscous flow and the fourth emerges due to the chemical reactions, described with affinities..

The heat flow is given by

where the first term describes the "pure" heat conduction, the second describes the heath transfer due to diffusion - Soret effect.

The diffusion flow is described by

where the first term arises due to the thermodiffusion and the second due to the "pure" diffusion. The quantities

are the kinetic coefficients connected with the heat conduction, diffusion and crossover effects coefficients.

 

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